The results provide another example of β-elimination reactions poised near the E2-E1cB mechanistic borderline. The approximately 50-fold greater reactivity of the 2- and 4-cyano substrates is attributed to the influence of the electron withdrawing cyano group in the deprotonation step. Computational results indicate that deprotonation of the H-bonded complex is probably barrier free, and is accompanied by simultaneous loss of the leaving group (E2) for L = Cl, Br, and I, but with subsequent, rapid loss of the leaving group (E1cB-like) for the poorer leaving groups, CN and F. The reactions are second-order in, the mechanism involving rate determining hydrogen-bond formation between piperidine and the substrate-piperidine addition intermediate followed by deprotonation of this intermediate. Change in reactivity while going down in the group: Generally, metal reactivity decreases from left to right cross periods and increases down the group. They are placed vertically in the column, second from the right in the periodic table. The Group 7 elements are called halogens. A different leaving group order is observed in the substitution reactions of ring-substituted N-methylpyridinium compounds with piperidine in methanol: 2-CN ≥ 4-CN > 2-F ∼ 2-Cl ∼ 2-Br ∼ 2-I. Solution Halogen: Halogen is a salt-forming compound. As a result the temperature required to break these bond decreases.The “element effect” in nucleophilic aromatic substitution reactions (S NAr) is characterized by the leaving group order, L = F > NO 2 > Cl ≈ Br > I, in activated aryl substrates. The strength of the covalent bond decreases down the group as the halogen atom increases in size and distance between the atomic nuclei and the shared pair of electrons increases. Thermal stability of hydrogen halides decreases down the group.As we go down the group the reaction becomes less vigorous. Halogens form covalent bonds with hydrogen to form hydrogen halide molecules. The trend of reactivity of halogen is illustrated by their reactions with hydrogen.Reactions between halogens and Group 1 and Group 2 metals are typical redox reaction with Group 1 and Group 2 metals being oxidised from an oxidation state of 0 to an oxidation state of 1+ and 2+ respectively. Halogens react with Group 1 and Group 2 metals to form halide salts.To identify the halogen present in the solution you look out for the colour change and compare it to the table below Displacement reactions can also be used to identify the halogen present in the solution.It is worth to note here that a halide in solution will only be displaced by a halogen that is above it in the periodic table. The oxidising strength of the halogens can be compared by carrying out displacement reactions involving the halide ions. Displacement reactions are a good test for oxidising ability.Halogens become less oxidising as you move down the group as it is more difficult to gain an electron. Remember that oxidation is a gain of electrons. As the halogens become less reactive down the group, their oxidising ability decreases.This is why the reactivity decreases down the group. There is a reduced attraction between the nucleus and the outermost shell so it is more difficult to gain an extra electron. Halogens become less reactive as you move down the group as the atomic radius of the element increases which means that the distance between the outer shell of electrons and the nucleus increases.
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Our Friends (those who promote us are in bold): (This is a place for memes, not propaganda.) All of your historical jokes and memes go here. There was no place to be a redditor in history. This subreddit was created because there was a niche that was not being filled in the historical Reddit community. isos are presented in the UI compared to how. The latest film to arrive is the Lego Batman Movie, hence why I am wondering whether it might be worth doing something to pull off the extras too.Īny difference in the way. mkv of the film only and ditch the extras. Conversion of some DVDs could fail at the very end of title MakeMKV v1.16.3 ( ) Bug fixes. I want to reduce the minimum title length down to something smaller, or at the very least, be able to rip. 1.17.0 regressions: On some UHD HEVC streams program spitted thousands of invalid 'Corrupt' messages, appearing to hang Program crashed decoding certain AC3 (DD) streams, usually during transcoding MakeMKV v1.17. Of course, if you're guess wrong, you have to re-rip. In the log, I keep finding lines of text like this one after scanning the contents of the disc: 'Title 4 has length of 106 seconds which is less than minimum title length of 120 seconds and was therefore skipped'. During the rip, MakeMKV reported that it was assembling the play list from a LOT of different m2ts files, though. Some go with the theory that the longest one is usually the main one and then take a chance and only rip that one. Joined: Sun 11:21 pm Re: Star Wars Rogue One by Woodstock Sat 12:32 pm I selected 00800 when I ripped Rogue One, and it appears to be correct. ISO give me the film and all the extras, loading as if I had the physical media in a BD player? Currently I make a. MakeMKV - software to convert blu-ray and dvd to mkv. mic j said: After the MakeMKV scan, you can only guesstimate which is the title you are truly interested in. Organisation on the NAS: currently I put each film in its own folder and the folder name is that of the film. Segment 2: French text intro (41secs, identical runtime to seg 1).I used the first two segments of Rogue One for the test since it has several intro segments (. I could do with a little bit of help/insight before jumping though:Īre there any must dos/must not dos when ripping to a. However, as I acquire more films I’m wondering whether to switch to using. Here are how the tracks layed out (including the bonus features) for the Disney Movie Club US disc. Having ripped my collection (500+ films) before ISO support was launched by appetite to redo them all as ISOs has been, ummm, limited… But Rogue One has 7 different titles, instead of 4. I’ve been happily using Makemkv to prodcue. Now press 'rename' and youre nearly done: In a final step move all mkv files to '/Showname (2019)/' and delete all empty 'discXY/' subfolders. There are lots of ways you can make a shirt for the 100th day of school. Learning and fun, plus a craft activity…I’m in! How to Make 100 Day of School Shirt She said that not only is it a milestone, but it is also a great way for them to teach various mathematical concepts using the number 100 in a fun and creative way. Why is it important you ask? I wondered the same thing so I asked my sister who is a kindergarten teacher why the 100th day of school was such a big deal. The 100th day of school is literally the 100th day of the school year. When I asked my daughter what she wanted to use to create her 100th day of school shirt she said “Bubblegum!” Since gluing 100 pieces of bubble gum to a shirt wasn’t ideal I came up with the next best thing, a cute DIY Bubblegum shirt using DecoArt SoSoft paints. Most of these shirts generally involve attaching 100 of any object to the shirt along with a clever phrase or saying. Many elementary schools celebrate the completion of 100 days of school by having their students create customized 100th Day of School shirts. Colorful bricks are on this shirt that says I stacked up 100 days.Whether you have survived 100 days of at-home learning or 100 days at school this is a milestone worth celebrating! Commemorate the occasion with this quick and easy DIY 100 Sweet Days of School Bubblegum Shirt. This is a great shirt for the brick lover in your family. We could all use bright and happy these days so it’s perfect. Multiple colors and sizes availableĪ bright and colorful baseball style shirt, this one comes in a variety of colors. With social distancing a big part of the school experience, this shirt says it all for this different year. It comes in different sizes and colors and can be customized with a name.Ī shirt for older kids and fans of Among Us, this shirt is a great way to mark the 100th day of school. What a monster of a shirt! This says this little monster is 100 days smarter and has cute monsters on it. It comes in both adult sizes and kids sizes and the tie dye is very much in style right now.Ī unique crayon box shirt to keep count of the 100 days of school. I survived 100 Masked school days tie dye shirtĪ fun tie dye shirt, this says I survived 100 days masked. Perfect for the gamer students in your life, this fun shirt says 100 days, achievement unlocked and comes in multiple colors and sizes.īright and colorful this cheerful top is printed on a dark colored shirts making the colors really pop. Perfect for teachers doing school online and virtually, this shirt pokes fun of the way most online classes are being held, via zoom. This year due to some kids being in school, but many being virtual, we rounded up some fun 100 days of school shirt ideas that students and even teachers could wear to commemorate this special day. Some schools even have their student’s dress up to look like a 100 year old and predict what life will be like when they are 100. Schools typically have projects in class and practice counting to 100. One important day in a younger student’s academic year is the 100th day of school. Follow us on Instagram for more fun ideas for kids! Most kids are learning virtually and these creative 100 Days of School Shirt Ideas reflect this crazy and unique 2021 School Year. By using this site, you agree to our Terms of Use. This is also the first telescope we have seen come out of Celestron where it seems that a highly competent styling designer was consulted it is a very attractive telescope with nicely made, finished, and well fitted components. Some of the features found in the Celestar 8 Deluxe and Ultima 2000 Computer Controlled telescopes which suit them better to long term "Deep Sky" astrophotography ("Fastar" capability, CCD auto guider port, Periodic Error Control, etc.), and manual controls were purposely omitted on the NexStar in order to provide the same high quality of SCT view which Celestron is known to be capable of, with the "Go-To" capability at moderate cost. The NexStar 8 (with appropriate optional hardware) is also suitable for short exposure imaging of planets, the moon or the Sun (with suitable filter). The ability to precisely move the telescope up or down or left or right (without the astronomical clock drive continuously moving the telescope) makes this a platform to be considered for terrestrial and other applications where exact positioning is required. This will be a telescope to be considered by those who are interested primarily in visual applications, or for the photography of terrestrial objects including birds or other wildlife at great distances. We will continue to accept names on our non-binding waiting list for notification when the new 11 inch telescopes become available - assuming they too meet our expectations.Ĭelestron developed this telescope in order to provide a relatively affordable, very easy to use "Go-To" computer controlled telescope with better rigidity than the Celestar 8 telescope. The demand for the Ultima 2000 remains high so Celestron has made no decision on it's future.Ĭompany Seven expects to see an 11" Fastar model, and probably an 11" using the NexStar OS following in Spring 2001 at the earliest. The NexStar 8 may not replace the Ultima 2000, it compliments the line with a more affordable simpler to use interface, geared for visual applications. Company Seven will revise this article as is appropriate after we gain experience with production models (we already have the NexStar 8 on display). We anticipated larger telescopes and in February 2000, Celestron announced the NexStar 8 - first deliveries began in March 2000. Celestron introduced their third generation operating system (OS) with the NexStar 5 in August 1999 since then the telescope has come to meet its advertised expectations. In August 1996 their second generation of computer controlled telescope the Ultima® 2000 arrived. NOTE: In 1985 Celestron became the first company to offer computer-driven Schmidt-Cassegrain telescopes - the "CompuStar" series. Left: Celestron NexStar 8 viewed from front and left (36,739 bytes). Company Seven | Celestron NexStar 8 Schmidt-Cassegrain Computer Controlled TelescopeĬ-7 Home Page C-7 News Consignment Library Products & Services Product Lines Order Search C7.comĬelestron History Distribution News Notes & Interesting Articles Products Pricing Quality AssuranceĬelestron NexStar 8 Schmidt-Cassegrain TelescopeĬlick on image for enlarged view (159,393 bytes) Do not make a lot of torches or burning barrels, as they cause a huge fps drop when too many are placed around your base. Performance wise this game has random fps drops around cities and on modded servers. If you don’t like to play alone, you can always make some allies and party up with players you can trust, but if you stay in a group on horde night, it means a lot more zombies will come so be careful. One feature I like about this game is that you can break buildings, cut up bodies, or recycle items to get the materials you are looking for. There are a couple of traders on the map you can get missions from or just buy and sell items to, but make sure you keep their bases alive as they will not respawn if they die. Be careful when building, as structural integrity is calculated, which means if you build too much or the building does not have enough support, it will start to collapse. The building system is unique with 100s of things, so you should have no problem building the type of base you want- even one with turrets. You can change the settings to match the survival experience you want. For example, you can choose for the enemy to always walk or run, or be very strong or weak, or even how long it takes for you to start to get hungry and thirsty. The menu and options are very easy to use. They grow stronger and harder depending on how many days have passed on the server or your single player save, but you can choose the settings and change them into something that you can enjoy playing. Horde Night is just as bad as it sounds and comes every seven days, so be prepared to run or fight, as zombies will know where you are and try to kill you until the night is over, but you will get a lot of loot if you survive and kill them. There are tons of buildings to explore in a fully destructible map right down to bedrock (unless it’s protected by a player claim block as some servers don’t allow base raiding) Once you start the game you will find yourself spawning on a huge map with a few items and some instructions to help you get started. This has to be one of my favourite games and has gone through many improvements since its release on 13 December 2013. Conan Exiles – Mounts guide and map locations.Last Oasis Quality Guide with Tips & Tricks.Conan Exiles Rhino Guide and Map Locations.Conan Exiles – Isle of Siptah Achievement Guide.Top 10 tips to help you master Planet Zoo.Clue/Cluedo: The Classic Mystery Game Review.Metal Gear Solid V: The Phantom Pain Review.Cyanide & Happiness – Freakpocalypse Review.Shadow Tactics: Blades of the Shogun – Aiko’s Choice. These colors are perfect when you are going on a date because they are sexy and mysterious colors. On the other hand, to create a mysterious vibe, you will want to try deep maroon and plum shades. Deeper shades, like scarlet or cranberry, are also perfect for an evening out. It is a fun color that sends the message you're out to have a fun time. If you're just out at a nighttime haunt, candy apple red is a perfect shade. They are perfect for stirring up romance on a date or an evening out. Shades of red, purple, and burgundy create a sexy look. For example, ILNP's pink holographic nail polish is the perfect color because it is subtle yet beautiful.Ĭlick here to check out ILNP's Dusky Pink Holographic nail polish on Amazon! Red, Purple, And Burgundy These colors will lessen the sharpness of the black in the dress. If you want something a little more flashy, you can try an iridescent white or a holographic gray. You will look fabulous, and your makeup will complement the dress well without distracting the eye. By using a more subtle color, you can wear light makeup and put all the attention onto your dress. Whether you are going to a business meeting or a casual meetup with friends, these colors are perfect. They will make you look classy and refined. Neutral colors can include gold, silver, gray, white, and nude colors like beige and light pink. Nail Colors To Wear With A Black Dress Neutral Colors And Whites We will also discuss whether or not you should match your nails to your dress and if your nail polish should match your makeup. Now that you know a little bit about what colors you can try, continue reading for more details about different looks to try and to find out what colors not to wear with a black dress. A french manicure on your hands with red toenails will also have this effect. If you want to stand out and turn heads, try a bolder color like lavender, electric blue, or mint green.To strike up a sexy mood for a date, choose red, purple, or burgundy shades.Neutral colors are perfect for almost any event. However, the color you want to paint your nails depends on what event you are going to and what mood you want to portray. As a result, almost every color will match your dress. The color black matches almost everything. That's why we took the time to check out the latest fashion trends so you can easily pair your dress with your polish. However, it can be tricky to find out what nail polish color will enhance your look. Black dresses are elegant and can make anyone look elegant and beautiful. What has occurred is AMC's debt has ballooned. So from 2014 through 2016 large amounts of capital were expended on renovations and acquisitions that have done absolutely nothing for AMC's bottom line. The chart below shows the revenue breakdown. The biggest result of these acquisitions was that AMC expanded internationally into Europe. exhibitor, as the chart above shows, it actually did nothing for the bottom line every year thereafter. While this helped make headlines that AMC was now the largest U.S. The next big change that occurred was at the end of 2016 when AMC made a series of acquisitions under their newest CEO Adam Aron. The reductions in capacity just could not be made up by ticket and concession price increases. 2013, net income actually decreased by more than $250 million each year. Did the investment improve results? Not even a little. Other theatre chains made similar theatre seating redesigns. After a grace period ticket prices were raised by just $1-2. The total cost of the renovations was $600 million. In doing so he reduced theatre capacities by 50-70%. Despite flat revenues for years before, then CEO Gerry Lopez made the questionable decision in 2014 to change out the seats in many theatres in their network with new Lay-Z-Boy recliner style seating. (all graphs by the author) Where we have been and where we are nowĪs I discussed in my last article, "AMC Apes: More Hurt Than Help", domestic box office revenues peaked way back in 2016. Even as we move through what we hope will be the final months of Covid impacts, AMC has little hope of returning to the attendance numbers of 2017 to 2019. But the failure as I see it, for the entire industry, is blinding themselves to the new reality since 2019: And it is all about the pandemic with streaming being the studios' vaccine. In all honesty, you have to hand it to AMC CEO Adam Aron for doing the best that could be done with his hands tied behind his back while swimming upstream in 20. You might also pay a stockbroker commission or fees when buying and selling stocks.The movie theatre industry has been in peril for years due to declining revenues and attendance. Stocks are more normally bought and held for longer. Which makes them more suited to short-term trading opportunities. In the UK, there is no stamp duty on CFD trading, but there is when you buy stocks.ĬFDs attract overnight costs to hold the trades, (unless you use 1-1 leverage) But with traditional stock trading, you buy the shares for the full amount. However, with traditional stock trading you enter a contract to exchange the legal ownership of the individual shares for money, and you own this equity.ĬFDs are leveraged products, which means that you only need to deposit a percentage of the full value of the CFD trade in order to open a position. You can still benefit if the market moves in your favour, or make a loss if it moves against you. With CFDs, you never actually buy or sell the underlying asset that you’ve chosen to trade. The main difference between CFD trading and stock trading is that you don’t own the underlying stock when you trade on an individual stock CFD. Read more: Ape army pushes AMC stock to four-year high In August, AMC beat both earnings and revenue estimates as the cinema chain outlined plans including a move into digital payments as well as airing live events. No financial data or figures were issued by AMC in its statement. October saw the release of the Daniel Craig headlined James Bond movie No Time to Die, the Tom Hardy comic book action movie Venom: Let There Be Carnage and the latest big-screen adaptation of Dune, the influential 1965 sci-fi novel from Frank Herbert.ĪMC also said "October 2021 ticket admission revenues at AMC’s international theatre locations also were the highest of any month since the pandemic."ĪMC owns the Odeon Cinemas Group, UCI Cinemas and the Nordic Cinema Group. In a statement released Sunday, AMC said "domestic industry box office for October 2021 is estimated to come in considerably higher than that of any previous month since February of 2020." Covid-19 forced the closure of movie theatres across the US in March of last year. The largest US movie exhibition company confirmed the highest monthly ticket revenues since the forced closure of theatres early last year. An AMC cinema in Marlton, NJ – Photo: ĪMC Entertainment Holdings shares rose 4% on Monday as the cinema chain confirmed October box office numbers and set a date for third-quarter earnings.Īs at 11:10am EDT (UTC-4) shares were up 4% to $36.76 on the New York Stock Exchange. We bring you multiple options to pick up a favorite pair of mens jeans for sale online from the comfort of your living room. ring of fire jeans slim mens size 36 x 32 patched stretch medium wash denim blue 12.99 8.50 shipping SPONSORED Ring of Fire Mens Short Sleeve Black Graphic T-Shirt Bear Size Large 14.00 Was: 70. Whether you want to create a relaxed look or party look, the jeans pair with a plethora of options in both top wear and shoes to create a chilled outlook or a crisp look. Slim fit jeans for mens online bring you option to look slimmer and sassier. The Ring of Fire, also referred to as the Circum-Pacific Belt, is a path along the Pacific Ocean characterized by active volcanoes and frequent earthquakes. 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Investment in shares may not bring desired profits, leaving you cash-strapped. It would be in your interest to focus your attention towards money-making schemes. On the economic front, you need to be careful with your spending. Students may perform well on their academic front. Plans to travel to a far-off place with your friends may turn out to be very fruitful. You are likely to make decisions very quickly, which are in accordance to your scheme of things, plans and desires. When the time is right, you may take the big leap. Your optimistic approach may make you a fan favorite. You won’t compromise on quality and put in your best efforts to get your work done in the best way possible. Your soaring confidence levels may take you to higher grounds and slowly but steadily, you may take over leadership positions. You may not want to wait for opportunities and you are most likely to go out and create them for yourself. Today, you may be willing to take risks and go the extra mile for your own good. Things can get downright ugly when Leo pride ignores someone else's right to a mind of their own.PISCES (Feb 20-Mar 20) Students may perform well on their academic front. Make sure you really have the other person's best interests at heart, and don't just want to dominate them. When that advice is offered, Leos expect it to be followed to the letter. The trouble is, Leo pride refuses to admit that it is ever wrong about anything. Like the King of Beasts that is their zodiac symbol, Leos like to be the boss, and expect everyone to defer to them. Their pride and dignity makes them the kind of person others naturally look up to, and are always first to offer advice and counsel. Leos enjoy company and love to spoil everyone and share their own good fortune. Ruled by the Sun, they love to shine and are great extroverts. Leos are good at being warm hearted, generous and kind. Already, just having the planets of love and communication in your sign at the same time is putting heart and mind on the same page, but they are set to become even more aligned during Mercury's final days. Instead, with Venus slowing down and about to turn retrograde, they will soon start moving closer. It is while this is still in the spotlight that there is a chance to simply be aware.įor Venus to have returned to Leo over a month before Mercury returned should mean that they have no chance of catching up. As the North Node spends its last full day in your career sector and the South Node its last in your home and family sector they are vying for your attention as they have done every day for the last 18 months. It has been a few days since the Moon crossed the lunar nodes for the last time while they are policing your work/life balance, long enough to ensure the emotional fog of war is gone but recent enough so that you can still see clearly both sides of life's fence. |
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